– Cover features –

Chemistry, A European Journal (August 2019)
Magnetochemistry (December 2022)

– Publications –

2022

R. T. Marques, F. F. Martins, D. F. Bekiş, A. I. Vicente, L. P. Ferreira, C. S. B. Gomes, S. Barroso, V. Kumar, Y. Garcia, N. A. G. Bandeira, M. J. Calhorda, P. N. Martinho, “The halogen effect on the magnetic behaviour of dimethylformamide solvates in [Fe(halide-salEen)2]BPh4”, Magnetochemistry 2022, 8, 162. DOI: 10.3390/magnetochemistry8120162.

K. Pandurangan, A. B. Carter, P. N. Martinho, B. Gildea, T. Lemma, S. Shi, A. Sultan, T. E. Keyes, H. Müller-Bunz, G. G. Morgan, “Steric quenching of Mn(III) thermal spin crossover: Dilution of spin centers in immobilized solutions”, Magnetochemistry, 2022, 8, 8. DOI: 10.3390/magnetochemistry8010008.

2021

S. Friães, S. Realista, C. S. B. Gomes, P. N. Martinho, B. Royo, “Click-derived triazoles and triazolylidenes of manganese for electrocatalytic reduction of CO2”, Molecules, 2021, 26, 6325, DOI: 10.3390/molecules26216325.

S. Friães, S. Realista, C. S. B. Gomes, P. N. Martinho, L. F. Veiros, M. Albrecht, B. Royo, “Manganese complexes with chelating and bridging ditriazolylidene ligands: synthesis and reactivity”, Dalton Trans., 2021, 50, 5911-5920, DOI: 10.1039/D1DT00444A.

M. A. Bento, S. Realista, A. S. Viana, A. M. Ferraria, P. N. Martinho, “Cryptand-functionalized highly oriented pyrolytic graphite electrodes”, Sustainability, 2021, 13, 4158. DOI: 10.3390/su13084158.

2020

J. Pecak, W. Eder, B. Stöger, S. Realista, P. N. Martinho, M. J. Calhorda, W. Linert, K. Kirchner, “Synthesis, characterization, and catalytic reactivity of {CoNO}8 PCP pincer complexes”, Organometallics, 2020, 39, 2594-2601. DOI: 10.1021/acs.organomet.0c00167.

S. Realista, B. Oliveira, J. Aldeias, V. Fernández-Moreira, M. C. Gimeno, A. S. Viana, M. J. Calhorda, P. N. Martinho, “Structural and electronic properties in asymmetric binuclear Zn(II) amphiphilic compounds”, J. Coord. Chem., 2020, 73, 634-652. DOI: 10.1080/00958972.2020.1737325.

P. N. Martinho, F. F. Martins, N. A. G. Bandeira, M. J. Calhorda, “Spin crossover in 3d metal centers binding halide-containing ligands: magnetism, structure and computational studies”, Sustainability, 2020, 12, 2512. DOI:10.3390/su12062512.

2019

S. Realista, J. C. Almeida, S. A. Milheiro, N. A. G. Bandeira, L. G. Alves, F. Madeira, M. J. Calhorda, P. N. Martinho, “Co(II) cryptates convert CO2 into CO and CH4 under visible light”, Chem. Eur. J., 2019, 25,11670–11679 (hot paper). DOI: 10.1002/chem.201901806.

A. I. Vicente, X. Wu, Y. Ortin, L. P. Ferreira, M. D. Carvalho, S. Realista, A. Barker, G. G. Morgan, N. Galamba, P. J. Costa, M. J. Calhorda, P. N. Martinho, “Directing self-assembly in solution towards improved cooperativity in Fe(III) complexes with amphiphilic tridentate ligands”, Dalton Trans., 2019, 48, 4239-4247. DOI: 10.1039/C9DT00032A.

Earlier publications

P. N. Martinho, I. Kuehne, B. Gildea, G. McKerr, B. O’Hagan, T. Keyes, T. Lemma, C. Gandolfi, M. Albrecht, G. G. Morgan, “Self-Assembly properties of amphiphilic iron(III) spin crossover complexes in water and at the air-water interface”, Magnetochemistry, 2018, 4, 49. DOI: 10.3390/magnetochemistry4040049.

F. F. Martins, A. Joseph, H. P. Diogo, M. E. Minas da Piedade, L. P. Ferreira, M. D. Carvalho, S. Barroso, M. J. Romão, M. J. Calhorda, P. N. Martinho, “Irreversible magnetic behaviour caused by the thermosalient phenomenon in an iron(III) spin crossover complex”, Eur. J. Inorg. Chem., 2018, 2018, 2976-2983. DOI: 10.1002/ejic.201800605.

A. I. Vicente, L. P. Ferreira, M. D. Carvalho, V. H. N. Rodrigues, M. M. Dîrtu, Y. Garcia, M. J. Calhorda, P. N. Martinho, “Selecting the spin crossover profile with controlled crystallisation of mononuclear Fe(III) polymorphs”, Dalton Trans., 2018, 47, 7013-7019. DOI: 10.1039/C8DT00227D.

S. Realista, S. Quintal, P. N. Martinho, A. I. Melato, A. Gil, T. Esteves, M. D. Carvalho, L. Ferreira, P. D. Vaz, M. J. Calhorda, “Electrochemical studies and potential anticancer activity in ferrocene derivatives”, J. Coord. Chem., 2017, 70, 314-327. DOI: 10.1080/00958972.2016.1257125.

S. Realista, A. J. Fitzpatrick, G. Santos, L. P. Ferreira, S. Barroso, L. C. J. Pereira, N. A. G. Bandeira, P. Neugebauer, J. Hrubý, G. G. Morgan, J. van Slageren, M. J. Calhorda, P. N. Martinho, “A Mn(III) single ion magnet with tridentate Schiff-base ligands”, Dalton Trans., 2016, 45, 12301-12307. DOI: 10.1039/C6DT02538B.

S. Realista, P. Ramgi, B. P. Cardoso, A. I. Melato, A. S. Viana, M. J. Calhorda, P. N. Martinho, “Heterodinuclear Ni(II) and Cu(II) Schiff base complexes and their activity in oxygen reduction”, Dalton Trans., 2016, 45, 14725-14733. DOI: 10.1039/C6DT01903J.

A. I. Vicente, A. Joseph, L. P. Ferreira, M. D. Carvalho, V. H. N. Rodrigues, M. Duttine, H. P. Diogo, M. E. M. da Piedade, M. J. Calhorda, P. N. Martinho, “Dynamic spin interchange in a tridentate Fe(III) Schiff-base compound”, Chem. Sci., 2016, 7, 4251-4258. DOI: 10.1039/C5SC04577K.

A. J. Fitzpatrick, P. N. Martinho, B. J. Gildea, J. D. Holbrey, G. G. Morgan, “Robust room temperature hysteresis in an FeIII spin crossover metallomesogen”, Eur. J. Inorg. Chem., 2016, 2016, 2025-2029. DOI: 10.1002/ejic.201501335.

S. Realista, A. S. Viana, B. P. Cardoso, A. M. B. do Rego, P. D. Vaz, A. I. Melato, P. N. Martinho, M. J. Calhorda, “Asymmetric binuclear Ni(II) and Cu(II) Schiff base metallopolymers”, RSC Adv., 2015, 5, 39495-39504. DOI: 10.1039/C5RA03560K.

B. de P. Cardoso, A. I. Vicente, J. B. J. Ward, P. J. Sebastião, F. V. Chávez, S. Barroso, A. Carvalho, S. J. Keely, P. N. Martinho, M. J. Calhorda, “Fe(III) SalEen derived Schiff base complexes as potential contrast agents”, Inorg. Chim. Acta, 2015, 432, 258-266. DOI: 10.1016/j.ica.2015.04.026.

P. N. Martinho, E. J. Devid, M. V. Kamalakar, Ú. Prendergast, J-F. Dayen, V. Meded, T. Lemma, R. González-Prieto, F. Evers, T. E. Keyes, M. Ruben, B. Doudin, “Spin transition in arrays of gold nanoparticles and spin crossover molecules”, ACS Nano, 2015, 9, 4496–4507. DOI: 10.1021/acsnano.5b01103.

P. N. Martinho, E. J. Devid, M. V. Kamalakar, Ú. Prendergast, C. Kübel, T. Lemma, J.-F. Dayen, T. E. Keyes, B. Doudin, M. Ruben, S. J. van der Molen, “The influence of molecular mobility on the properties of gold nanoparticle organic ligand networks”, Beilstein J. Nanotechnol., 2014, 5, 1664-1674. DOI:10.3762/bjnano.5.177.

J. Kitchen, T. Gunnlaugsson, G. Morgan, P. N. Martinho, “Synthesis, crystal structures and EPR spectroscopic analysis of copper complexes featuring N-pyridyl-4-nitro-1,8-naphthalimide ligands”, Dalton Trans, 2014, 43, 6468-6479. DOI: 10.1039/C3DT53323A.

P. N. Martinho, Ana I. Vicente, Sara Realista, Marta S. Saraiva, Ana Melato, Liliana P. Ferreira, Maria de Deus Carvalho, “Solution and solid state properties of Fe(III) complexes bearing N-ethyl-N-(2-aminoethyl)salicylaldiminate ligands”, J. Organomet. Chem., 2014, 760, 48-54. DOI: 10.1016/j.jorganchem.2013.12.028.

P. N. Martinho, C. Rajnak, M. Ruben, “Nanoparticles, thin films and surface patterns from spin-crossover materials and electrical spin state control”, Spin-Crossover Materials: Properties and Applications, 2013, 375–404. Wiley, Book Chapter. DOI: 10.1002/9781118519301.ch14.

P. N. Martinho, B. Gildea, M. M. Harris, T. Lemma, A. D. Naik, H. Müller-Bunz, T. E. Keyes, Y. Garcia, G. G. Morgan, “Cooperative spin transition in a mononuclear Mn(III) complex”, Angew. Chem. Int. Ed., 2012, 51, 11995-11999. DOI: 10.1002/anie.201205573.

P. N. Martinho, T. Lemma, G. Picardi, B. Gildea, R. J. Forster, T. E. Keyes, G. Redmond, G. G. Morgan, “Template assembly of spin crossover 1D nanowires”, Angew. Chem. Int. Ed., 2012, 51, 12597-12601. DOI: 10.1002/anie.201205122.

P. N. Martinho, Y. Ortin,  B. Gildea,  C. Gandolfi,  G. McKerr,  B. O’Hagan,  M. Albrecht, G. G. Morgan, “Inducing hysteretic spin crossover in solution”, Dalton Trans, 2012, 41, 7461-7463 (hot communication). DOI: 10.1039/c2dt12036d.

C. Gandolfi, T. Cotting, P. N. Martinho, V. K. Malik, C. Bernhard, O. Sereda, A. Neels, G. G. Morgan, M. Albrecht, “Synthesis and self-assembly of spin-labile and redox-active manganese(III) complexes”, Dalton Trans, 2011, 40, 1855-1865. DOI: 10.1039/c0dt01222j.

C. Gandolfi, N. Miyashita, D. Kurth, P. N. Martinho, G. G. Morgan, M. Albrecht, “Organization of potentially spin- and redox-labile metal centers into Langmuir and Langmuir-Blodgett films”, Dalton Trans., 2010, 39, 4508-4516 (Cover). DOI: 10.1039/b926023d.

P. N. Martinho, C. J. Harding, H. Müller-Bunz, M. Albrecht, G. G. Morgan “Inducing spin crossover in Fe(III) amphiphiles”, Eur. J. Inorg. Chem., 2010, 675-679. DOI: 10.1002/ejic.200901183.

P. N. Martinho, S. Quintal, P. J. Costa, S. Losi, V. Félix, C. Gimeno, M. G. B. Drew, P. Zanello, M. J. Calhorda, “New polynuclear Mo-Fe complexes with benzimidazole ligands”, Eur. J. Inorg. Chem., 2006, 20, 4096-4103. DOI: 10.1002/ejic.200600296.

M. J. Calhorda, P. J. Costa, P. N. Martinho, M. C. Gimeno, A. Laguna, S. Quintal, M. D. Villacampa, “Synthesis and ligand properties towards gold and silver of the ferrocenylamidobenzimidazole ligand”, J. Organomet. Chem., 2006, 691, 20, 4181-4188. DOI: 10.1016/j.jorganchem.2006.06.025.